The great thing about this game is that there is no "wrong" way to build your character. You can specialize your character in anyway you want based on weapon preference, karma, speech preference, etc. I think a good starting build for S.P.E.C.I.A.L. is high on Intelligence (maybe a 9), Endurance and Luck and low on Charisma (maybe a 1 unless you want Speech opitions). As far a Skills go, early on you want lots of Lockpick, Science, Medicine, Repair and a weapon speciality of your choice. I wouldn't waste points on Barter and the same with Speech (unless you want Speech options). As far as Perks early on, I would use Intense Training on the first few levels and then Comprehension and Educated. There is no wrong way to play as long as you are having fun. For new characters I would also recommend stocking up on Nuka Cola Quantums as you play for a bonus later.